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Stabilization of Lithium Metal Anodes by Hybrid Artificial Solid Electrolyte Interphase

Type:
Journal
Info:
Chem. Mater. 2017, 29, 6298-6307
Date:
2017-07-06
DOI:
http://dx.doi.org/10.1021/acs.chemmater.7b01496

Author Information

Name Institution
Alexander Campbell KozenUniversity of Maryland
Chuan-Fu LinUniversity of Maryland
Oliver ZhaoUniversity of Maryland
Sang Bok LeeUniversity of Maryland
Gary W. RubloffUniversity of Maryland
Malachi NokedUniversity of Maryland

Films

Other LiPON

Hardware used: Veeco - Ultratech - Cambridge NanoTech Fiji
LiOt-Bu, LiOtBu, LTB, Lithium tert-butoxide, Lithium tertiary butoxide, LiOC4H9
CAS#: 1907-33-1
H2O, Water
CAS#: 7732-18-5
Trimethyl phosphate, TMP, (MeO)3PO
CAS#: 512-56-1
N2, Nitrogen
CAS#: 7727-37-9
Deposition Temperature = 150C

Film/Plasma Properties

Characteristic: Thickness
Analysis: Ellipsometry
Diagnostic: J.A. Woollam M-2000D

Characteristic: Chemical Composition, Impurities
Analysis: XPS, X-ray Photoelectron Spectroscopy
Diagnostic: Kratos Analytical Axis Ultra DLD

Characteristic: Battery Properties
Analysis: Two electrode coin cell
Diagnostic: MTI Corp.

Substrates

Li
Silicon

Notes

1025