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On the role of nanoporosity in controlling the performance of moisture permeation barrier layers

Type:
Journal
Info:
Microporous and Mesoporous Materials, Volume 188, April 2014, Pages 163-171
Date:
2014-01-10
DOI:
http://dx.doi.org/10.1016/j.micromeso.2014.01.013

Author Information

Name Institution
Alberto PerrottaEindhoven University of Technology

Films

Plasma Al2O3

Hardware used: Oxford Instruments FlexAL
TMA, Trimethylaluminum, Trimethylalumane, AlMe3, Al(CH3)3
CAS#: 75-24-1
O2, Oxygen
CAS#: 7782-44-7
Deposition Temperature Range = 25-100C

Plasma SiO2

Hardware used: Oxford Instruments FlexAL
BDEAS, SAM-24, Bis(diethylamino)silane, (Et2N)2SiH2
CAS#: 27804-64-4
O2, Oxygen
CAS#: 7782-44-7
Deposition Temperature Range = 25-100C

Film/Plasma Properties

Characteristic: Chemical Composition, Impurities
Analysis: FTIR, Fourier Transform InfraRed spectroscopy
Diagnostic: -

Characteristic: Thickness
Analysis: Ellipsometry
Diagnostic: -

Characteristic: Chemical Composition, Impurities
Analysis: RBS, Rutherford Backscattering Spectrometry
Diagnostic: -

Characteristic: Chemical Composition, Impurities
Analysis: TOF-ERDA, Time-Of-Flight Elastic Recoil Detection Analysis
Diagnostic: -

Characteristic: Chemical Composition, Impurities
Analysis: XPS, X-ray Photoelectron Spectroscopy
Diagnostic: -

Characteristic: Water Vapor Transmission Rate (WVTR)
Analysis: Calcium Test
Diagnostic: -

Characteristic: Porosity
Analysis: Ellipsometric Porosimetry (EP)
Diagnostic: -

Characteristic: Pore Size Distribution
Analysis: Ellipsometric Porosimetry (EP)
Diagnostic: -

Substrates

Notes

Oxford Instruments FlexAL PEALD Al2O3 and SiO2 moisture permeation barrier study.
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